Search results for "noble gase"

Noble gas magmatic signature of the Andean Northern Volcanic Zone from fluid inclusions in minerals

2021

Trace volatile elements like He are key for understanding the mantle source signature of magmas and to better constrain the relative roles of subduction and crustal processes to the variability of along-arc chemical and isotopic signatures of magmatic fluids. Here we report on noble gas abundances and isotopic data of Fluid Inclusions (FIs) in eruptive products and/or fumarolic gases from the Colombia-Ecuador segment of Andean Northern Volcanic Zone (NVZ). FIs in olivine phenocrysts from Ecuador (El Reventador, Cotopaxi and Tungurahua) yield air-normalized corrected He-3/He-4 ratios of 7.0-7.4 R-A, within the MORB range (8 +/- 1 R-A). With exception of the Cotopaxi lavas (opx = 50 km at the…

Geochemistry of Noble Gases and CO2 in Fluid Inclusions From Lithospheric Mantle Beneath Wilcza Góra (Lower Silesia, Southwest Poland)

2018

Knowledge of the products originating from the subcontinental lithospheric mantle (SCLM) is crucial for constraining the geochemical features and evolution of the mantle. This study investigated the chemistry and isotope composition (noble gases and CO2 ) of fluid inclusions (FI) from selected mantle xenoliths originating from Wilcza Góra (Lower Silesia, southwest Poland), with the aim of integrating their petrography and mineral chemistry. Mantle xenoliths are mostly harzburgites and sometimes bear amphiboles, and are brought to the surface by intraplate alkaline basalts that erupted outside the north-easternmost part of the Eger (Ohře) Rift in Lower Silesia. Olivine (Ol) is classified int…

Strongly SiO2-undersaturated, CaO-rich kamafugitic Pleistocene magmatism in Central Italy (San Venanzo volcanic complex) and the role of shallow dept…

2020

The Pleistocene (~460–265 ka) San Venanzo volcanic complex belongs to the IAP (Intra-Apennine Province) in central Italy, which comprises at least four small Pleistocene monogenetic volcanoes plus several unrooted pyroclastic deposits with peculiar mineralogical and whole-rock chemical compositions. San Venanzo products are strongly SiO2-undersaturated, CaO- and MgO-rich and show ultrapotassic serial character. The relatively common occurrence of calcite in the pyroclastic rocks and the overall high CaO content are interpreted in literature as primary mineral. The main rock facies at San Venanzo are calcite-rich scoria and lapilli tuffs, with minor massive lava flows, and a rare pegma…

A TWO-COMPONENT MANTLE EXTENDING FROM MT. ETNA TO HYBLEAN PLATEAU (EASTERN SICILY) AS INFERRED BY AN INTEGRATED APPROACH WITH NOBLE GASES, TRACE ELEM…

2012

Relativistic coupled cluster calculations of the electronic structure of KrH+, XeH+ and RnH+

2012

Potential energy curves of NgH+ cations (Ng = Kr, Xe, Rn) were obtained by using four-component relativistic CCSD(T) coupled cluster calculations. Dissociation energies, equilibrium bond lengths, electronic properties, such as dipole moments and electric field gradients at the nuclei, and the related spectroscopic parameters of the electronic ground state have been determined. The results obtained for KrH+ and XeH+ are in good agreement with available experimental data, while those for RnH+ have been determined for the first time at this level of theory.

An overview of the geochemical characteristics of oceanic carbonatites: New insights from Fuerteventura carbonatites (Canary islands)

2021

The occurrence of carbonatites in oceanic settings is very rare if compared with their continental counterpart, having been reported only in Cape Verde and Canary Islands. This paper provides an overview of the main geochemical characteristics of oceanic carbonatites, around which many debates still exist regarding their petrogenesis. We present new data on trace elements in minerals and whole-rock, together with the first noble gases isotopic study (He, Ne, Ar) in apatite, calcite, and clinopyroxene from Fuerteventura carbonatites (Canary Islands). Trace elements show a similar trend as Cape Verde carbonatites, almost tracing the same patterns on multi-element and REE abundance diagrams. 3…

The role of trapped fluids during the development and deformation of a carbonate/shale intra-wedge tectonic mélange (Mt. Massico, Southern Apennines,…

2020

Abstract Numerous studies exist on exhumed tectonic melanges along subduction channels whereas, in accretionary wedge interiors, deformation mechanisms and related fluid circulation in tectonic melanges are still underexplored. We combine structural and microstructural observations with geochemical (stable and clumped isotopes and isotope composition of noble gases in fluid inclusions of calcite veins) and U-Pb geochronological data to define deformation mechanisms and syn-tectonic fluid circulation within the Mt. Massico intra-wedge tectonic melange, located in the inner part of the central-southern Apennines accretionary wedge, Italy. This melange developed by shear deformation at the bas…

Recycled crustal carbon in the depleted mantle source of El Hierro volcano, Canary Islands

2021

The Canary Islands, in the eastern Atlantic, are among the most enigmatic Oceanic Island provinces on Earth, as the mantle source feeding its volcanism exhibits wide spatial heterogeneity and a multiplicity of sources. Multi-isotope whole-rock studies have long revealed the presence of a recycled oceanic crust/lithosphere component in the mantle source. However, noble gas systematics have been more challenging to interpret, and the available carbon isotope data is limited and cannot support/dismiss this interpretation. Here, we present the very first isotopic characterisation of CO2 and noble gases (He-Ne-Ar) in fluid inclusions (FI) in minerals hosted in mantle xenoliths from El Hierro, th…

Trace elements and noble gases (He, Ne, Ar) isotopic study of Fuerteventura carbonatites: implications for their mantle source

The composition of fluids stored in the central Mexican lithospheric mantle: Inferences from noble gases and CO2 in mantle xenoliths

2021

We present the first isotopic (noble gases and CO2) characterization of fluid inclusions coupled to Raman microspectroscopy analyses in mantle xenoliths from Central Mexico, a geodynamically complex area where the Basin and Range extension was superimposed on the Farallon subduction (terminated at 28 Ma). To characterize the isotopic signature of the Central Mexican lithospheric mantle, we focus on fluid inclusions entrapped in mantle xenoliths found in deposits of the Joya Honda maar (JH), a Quaternary monogenetic volcano belonging to the Ventura Espiritu Santo Volcanic Field (VESVF) in the state of San Luis Potosí (central Mexico). Thirteen ultramafic plagioclase-free xenoliths were selec…